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16 Essential Elements

An element is not considered essential unless a deficiency of it makes it impossible for the plant to complete its life cycle; such deficiency is specific to the element in question and can be prevented or corrected only by supplying this element; and the element is directly involved in the nutrition of the plant quite apart from possible effects in correcting some unfavorable microbial or chemical condition of the soil or other culture medium.   -D. I. ARNON
 

There are at present 16 Plant Nutrients which are known to be essential for the growth and reproduction of higher plants.  These elements are: carbon, hydrogen, oxygen, phosphorus, potassium, nitrogen, sulfur, calcium, iron, magnesium, boron, manganese, copper, zinc, molybdenum, and chlorine. Other nutrients which may be essential are colbalt, strontium, vanadium, silicon, and nickel though these are not considered essential by the world community for all plants and are not routinely applied as a fertilizer nutrient. As techniques for evaluating the essentiality of trace elements improve, it is generally believed that more elements will be added to the list of essential plant nutrients.

 

Discoverer and Discoverer of Essentiality for the Essential Elements (Glass, 1989).

 Element 

Discoverer 

Year

Discoverer of Essentiality

Year

C

** 

** 

De Saussure

1804

Cavendish 

1766 

De Saussu re 

1804

Priestley 

1774 

De Saussure 

1804

Rutherford 

1772 

De Saussure 

1804

Brand 

1772 

Ville 

1860

** 

** 

vonSachs, Knop 

1865

Davy 

1807 

vonSachs, Knop 

1860

Ca 

Davy 

1807 

vonSachs, Knop 

1860

Mg 

Davy 

1808 

vonSachs, Knop 

1860

Fe 

** 

** 

vonSachs, Knop 

1860

Mn 

Scheele 

1774 

McHargue 

1922

Cu 

** 

** 

Sommer 
Lipman & MacKinnon 

1931
1931

Zn 

** 

** 

Sommer & Lipman 

1926

Mo 

Hzelm 

1782 

Amon & Stout 

1939

Gay Lussac & Thenard

1808 

Sommer & Lipman 

1926

Cl 

Scheel 

1774 

Stout 

1954

 
Nutritional Deficiencies & Explanations
 
Functions Deficiency symptoms
Calcium (Ca)
1.  Constituent of cell walls in the form of calcium pectate; necessary for normal mitosis (cell division).

2.  Helps in membrane stability, maintenance of chromosome structure.

3.  Activator of enzymes (phospholipase, argine kinase, adenosine triphosphates).

4.  Acts as a detoxifying agent by neutralizing organic acids in plants.
 


1.  Calcium deficiencies are not often seen in the field because secondary effects associated with high acidity limit growth.

2.  The young leaves of new plants are affected first.  These are often distorted, small and abnormally dark green.

3.  Leaves may be cup-shaped and crinkled and the terminal buds deteriorate with some breakdown of petioles.

4.  Root growth is markedly impaired; rotting of roots occurs.

5.  Desiccation of growing points (terminal buds) of plants under severe deficiency.

6.  Buds and blossoms shed prematurely.

7.  Stem structure weakened.
 

Magnesium (Mg)
1.  Constituent of chlorophyll molecule and therefore essential for photosynthesis.

2.  An activator of many enzyme systems involved in carbohydrate metabolism, synthesis of nucleic acids, etc.

3.  Promotes uptake and translocation of phosphorus.

4.  Helps in movement of sugars within plant.


1. Interveinal chlorosis, mainly of older leaves, producing a streaked or patchy effect; with acute deficiency the affected tissue may dry up and die.

2.  Leaves usually small, brittle in final stages and curve upwards at margin.

3.  In some vegetable plants, chlorotic spots between veins, and marbling with tints of orange, red and purple.

4.  Twigs weak and prone to fungus attack, usually premature leaf drop.
 

Sulphur (S)
1.  Constituent of sulphur-bearing amino acids.

2.  Involved in the metabolic activities of vitamins, biotin, thiamine and coenzyme A.

3.  Aids stabilization of protein structure.
 


1.  Younger leaves turn uniformly yellowish green or chlorotic.

2.  Shoot growth is restricted, flower production often indeterminate.

3.  Stems are stiff, woody and small in diameter.

Iron (Fe)
1.  Necessary for the synthesis and maintenance of chlorophyll in plants.

2.  Essential component of many enzymes.

3.  Plays an essential role in nucleic acid metabolism affects RNA metabolism or chloroplasts.
 


1.  Typical interveinal chlorosis; youngest leaves first affected, points and margins of leaves keep their green color longest.

2.  In severe cases, the entire leaf, veins and interveinal areas turn yellow and may eventually become bleached.

Manganese (Mn)
1.  A catalyst in several enzymatic and physiological reactions in plants; a constituent of pyruvate carboxylase.

2.  Involved in the plant's respiratory process.

3.  Activates enzymes concerned with the metabolism of nitrogen and synthesis of chlorophyll.

4.  Controls the redox potential in plant cells during the phases of light and darkness.
 


1.  Chlorosis between the veins of young leaves, characterized by the appearance of chlorotic and necrotic spots in the interveinal areas.

2.  Greyish areas appear near the base of the younger leaves and become yellowish to yellow orange.

3.  Symptoms of deficiency popularly known in oats as "grey speck", in field peas as "marsh spot", in sugarcane as "streak disease''.

Boron (B)
1.  Affects the activities of certain enzymes.

2.  Ability to complex with various polyhydroxy-compounds.

3.  Increases permeability in membrane and thereby facilitates carbohydrate transport.

4.  Involved in lignin synthesis and other reactions.

5.  Essential for cell division.

6.  Associated with the uptake of calcium and its utilization by plants.

7.  Regulates potassium/calcium ration in plants.

8.  Essential for protein synthesis.
 


1.  Death of growing plants (shoot tips).

2.  The leaves have a thick texture, sometimes curling and becoming brittle.

3.  Flowers do not form and root growth is stunted.

4.  "Brown heart" in root crops characterized by dark spots on the thickest part of the root or splitting at center.

5.  Fruits such as apples develop "internal and external cork" symptoms.

Molybdenum (Mo)
1.  Associated with nitrogen utilization and nitrogen fixation.

2.  Constituent of nitrate reductase and nitrogenase.

3.  Required by Rhizobia for nitrogen fixation.


1.  Chlorotic interveinal mottling of the lower leaves, followed by marginal necrosis and infolding of the leaves.

2.  In cauliflower, the leaf tissues wither leaving only the midrib and a few small pieces of leaf blade ("whip-tail").

3.  Molybdenum deficiency is markedly evident in leguminous plants.
 

Chlorine (Cl)
1.  A constituent of auxin chloroindole-3-acetic acid which in immature seeds takes the place of indole acetic acid.

2.  Constituent of many compounds found in fungi and bacteria.

3.  Stimulates the activity of some enzymes and influences carbohydrate metabolism and water holding capacity of plant tissue.
 


1.  Wilting of leaflet tips, chlorosis of leaves and finally bronzing and drying.
Nitrogen(N)
1.  An important constituent of chlorophyll,            protoplasm, protein and nucleic.

2.  Increases growth and development of all living tissues.

3.  Improves the quality of leafy vegetables and fodders and the protein content of food grains. 
 
 

 


1.  Stunted growth.

2.  Appearance of a light-green to pale-yellow color on the older leaves, starting from the tips.  This is followed by death and/or dropping of the older leaves depending upon the degree of deficiency.

3.  In acute deficiency, flowering is greatly reduced.

4.  Lower protein content. 

Phosphorus (P)
1.  A constituent of phosphatides, nucleic acids, proteins, phospholipids and coenzymes NAD, NADP and ATP.

2.  Constituent of certain amino acids.

3.  Necessary for cell division, a constituent of chromosomes; stimulates root development.

4.  Necessary for meristematic growth; seed and fruit development; stimulates flowering.
 


1.  Overall stunted appearance, the mature leaves have characteristic dark to blue-green coloration, restricted root development.

2.  In acute deficiency, occasional purpling of leaves and stems; spindly growth.

3.  Delayed maturity and lack of or poor seed and fruit development.

Potassium (K)
1.  An activator of enzymes involved in photosynthesis and protein and carbohydrate metabolism.

2.  Assists carbohydrate translocation; synthesis of protein and maintenance of its stability; membrane permeability and pH control; water utilization by stomatal regulation.

3.  Improves utilization of light during cool and cloudy weather and thereby enhances plant ability to resist cold and other  adverse conditions.

4.  Enhances the plant's ability to resist diseases.

5.  Increases size of grains or seeds and improves the quality of fruits and vegetables. 
 


1.  Chlorosis along the leaf margins followed by scorching and browning of tips of older leaves; these symptoms then gradually progress inwards.

2.  Slow and stunted growth of plants.

3.  Stalks weak, and plants lodge easily.

4.  Shriveled seeds or fruits.

Zinc(Zn)
1.  Involved in the biosynthesis of indole acetic acid.

2.  Essential component of a variety of metallo-enzymes-carbonic anhydrase, alcohol dehydrogenase, etc.

3.  Plays a role in nucleic acid and protein synthesis.

4.  Assists the utilization of phosphorus and nitrogen in plants.


1.  Deficiency symptoms mostly appear on the 2nd or 3rd fully mature leaves from the top of plants.

2.  In maize, from light yellow striping to a broad band of white or yellow tissue with reddish purple veins between the midrib and edges of the leaf, occurring mainly in the lower half of the leaf.

3.  In wheat, a longitudinal band of white or yellow leaf tissue, followed by interveinal chlorotic mottling and white to brown necrotic lesions in the middle of the leaf blade; eventual collapse of the affected leaves near the middle.

4.  In rice, after 15-20 days of transplanting, small scattered light yellow spots appear on the older leaves which later enlarge, coalesce and turn deep brown; the entire leaf becomes rust-brown in color and dries out within a month.

5.  In citrus, irregular interveinal chlorosis; terminal leaves become small and narrowed (little-leaf); fruit-bud formation is severely reduced; twigs die back.
 

Copper(Cu)
1.  Constituent of cytochrome oxidase and component of many enzymes - ascorbic acid oxidase, phenolase, lactase, etc.

2.  Promotes formation of vitamin A in plants.
 
 

 


1.  In cereals, yellowing and curling of the leaf blade, restricted ear production and poor grain set, indeterminate tillering.

2.  In citrus, die back of new growth; exanthema  pockets of gum develop between the bark and the wood; the fruit shows brown excretions.

 

Table 17 (Major Cations In Water)

 

Constituents in Irrigation Water ---Major Cations

Constituent Symbol Equivalent 
Weight
Desirable
Range (ppm)
Desirable
Range (meq/L)
Comments
Calcium  Ca++  20.04 40-120 0.2-6.0 Essential plant nutrient, occurs naturally in most waters.  Low levels increase potential for Calcium deficient plants, but high levels are not normally harmful.
Magnesium  Mg++  12.15  6-24  0.5-2.0  Essential plant nutrient, occurs naturally in most waters.  Low levels increase potential for Magnesium deficient plants, but relatively high levels are not normally a problem.
Sodium  Na+  23.00  <50  <20  A non-essential nutrient, occurs naturally in most waters.  Can influence soil structure and plant uptake of Ca and Mg (see Sodium Adsorption Ratio below).
Potassium  K+  39.10  trace  trace  An essential nutrient, normally found in waters in small amounts.  Presence of more than trace amounts indicates waters may contain fertilizer.
Ammonium  NH4+  17.03  trace  trace  A source of Nitrogen (an essential plant nutrient).  Normally present in waters in small amounts.  More than trace amounts indicates water may contain fertilizer.

 

Table 18 (Major Anions In Ground Water)

Constituents in Irrigation Water ---Major Anions

Constituent Symbol Equivalent   Weight Desirable
Range (ppm)
Desirable
Range (meq/L) 
Comments
Sulfate SO4- 48.0 25-240 0.5-5.0 Contains Sulfate, an essential nutrient, occurs naturally in most waters.  Low levels increase potential for sulfur deficiency, but high levels are not normally harmful.
Chloride C1- 35.46 <70 <2.0 Occurs normally in most waters.  Plants require trace amounts.  High concentrations are toxic to sensitive plants.
Phosphate PO4- 94.97 trace  trace Contains phosphorus an essential nutrient, normally found in waters only in trace amounts.  The presence of more than small amounts indicates water may contain fertilizer or detergent.
Nitrate NO3- 62.01 <10 0.12 Source of Nitrogen, an essential nutrient, occurs normally only in small amounts.  Presence of more than trace amounts indicates water may contain fertilizer.  The EPA Drinking Water Standard is 10 ppm maximum.


 

Table 19 (Boron And Flouride)

                         Boron and Fluoride

Constituents  Symbol  Desired Range (ppm)  Comments
Boron  B <0.5 An essential plant nutrient, occurs normally in most water.  Low levels increase potential for Boron Deficiency.  High levels can be toxic to plants.  When evaluating Boron fertility, remember to include Boron supplied by fertilizer and growing medium.
Fluoride  <0.75 A non-essential nutrient that occurs in some waters and is often added to public drinking supplies.  High Fluoride concentrations can cause toxicity in sensitive plants.

 

Table 20 (Irrigation Water Classifications)

                         Qualitative Classification of Irrigation Waters

  Class 1 - 
Excellent to Good
Class 2 - 
Good to Injurious 
Class 3 - 
Injurious to Unsatisfactory
EC, ds / m Less than 1.0 1.0 - 3.0 More than 3.0
Boron, ppm Less than 0.5 0.5 - 2.0 More than 2.0
Sodium, percent Less than 60  60 - 75 More than 75
Chloride, me/L Less than 5  5 - 10 More than 10

 

Table 21 (Water Quality Indices)

                         Maximum Acceptable Water Quality - Indices for Bedding Plants

Variable Plug Production  Finish Flats and Pots
pH1 (acceptable range) 5.5 to 7.5 5.5 to 7.5
Alkalinity2 1.5 me/l 2.0 me/l
  (75 ppm)  (100 ppm)
Hardiness 3.0 me/l  3.0 me/l
  (150 ppm)  (150 ppm)
EC  1.0 mS  1.2 mS
Ammonium-N  20 ppm  40 ppm
Boron  0.5 ppm  0.5 ppm

Adapted from P.V. Nelson, Fertilization. Pp. 151-176. In:E. J. Holcomb (ed). Bedding Plants IV. A Manual on the Culture of Bedding Plants as a Greenhouse Crop, Ball Publishing, Batavia, IL (1994).  Used with permission.
1pH not very important alone; alkalinity level more important
 2Moderately higher alkalinity levels are acceptable when lower amounts of limestone are incorporated into the substrate during its formulation. Very high alkalinity levels require acid injection into water source.
3High hardness values are not a problem if calcium and magnesium concentrations are adequate and soluble salt level is tolerable.

 

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