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16 Essential Elements
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An element is not considered essential
unless a deficiency of it makes it impossible for the plant to
complete its life cycle; such deficiency is specific to the element in
question and can be prevented or corrected only by supplying this
element; and the element is directly involved in the nutrition of the
plant quite apart from possible effects in correcting some unfavorable
microbial or chemical condition of the soil or other culture medium.
-D. I. ARNON
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There are at present 16 Plant Nutrients
which are known to be essential for the growth and reproduction of
higher plants. These elements are: carbon, hydrogen, oxygen,
phosphorus, potassium, nitrogen, sulfur, calcium, iron, magnesium,
boron, manganese, copper, zinc, molybdenum, and chlorine. Other
nutrients which may be essential are colbalt, strontium, vanadium,
silicon, and nickel though these are not considered essential by the
world community for all plants and are not routinely applied as a
fertilizer nutrient. As techniques for evaluating the essentiality of
trace elements improve, it is generally believed that more elements will
be added to the list of essential plant nutrients.
Discoverer and Discoverer of
Essentiality for the Essential Elements (Glass, 1989).
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Element |
Discoverer |
Year |
Discoverer of Essentiality |
Year |
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C |
** |
** |
De Saussure |
1804 |
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H |
Cavendish |
1766 |
De Saussu re |
1804 |
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O |
Priestley |
1774 |
De Saussure |
1804 |
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N |
Rutherford |
1772 |
De Saussure |
1804 |
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P |
Brand |
1772 |
Ville |
1860 |
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S |
** |
** |
vonSachs, Knop |
1865 |
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K |
Davy |
1807 |
vonSachs, Knop |
1860 |
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Ca |
Davy |
1807 |
vonSachs, Knop |
1860 |
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Mg |
Davy |
1808 |
vonSachs, Knop |
1860 |
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Fe |
** |
** |
vonSachs, Knop |
1860 |
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Mn |
Scheele |
1774 |
McHargue |
1922 |
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Cu |
** |
** |
Sommer
Lipman & MacKinnon |
1931
1931 |
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Zn |
** |
** |
Sommer & Lipman |
1926 |
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Mo |
Hzelm |
1782 |
Amon & Stout |
1939 |
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B |
Gay Lussac & Thenard |
1808 |
Sommer & Lipman |
1926 |
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Cl |
Scheel |
1774 |
Stout |
1954 |
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Nutritional Deficiencies
& Explanations
| Functions |
Deficiency symptoms |
Calcium (Ca)
1. Constituent of cell walls in the form of calcium pectate;
necessary for normal mitosis (cell division).
2. Helps in membrane stability,
maintenance of chromosome structure.
3. Activator of enzymes (phospholipase,
argine kinase, adenosine triphosphates).
4. Acts as a detoxifying agent by
neutralizing organic acids in plants.
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1. Calcium deficiencies are not often seen in the field because
secondary effects associated with high acidity limit growth.
2. The young leaves of new plants are
affected first. These are often distorted, small and abnormally
dark green.
3. Leaves may be cup-shaped and crinkled
and the terminal buds deteriorate with some breakdown of petioles.
4. Root growth is markedly impaired;
rotting of roots occurs.
5. Desiccation of growing points (terminal
buds) of plants under severe deficiency.
6. Buds and blossoms shed prematurely.
7. Stem structure weakened.
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Magnesium (Mg)
1. Constituent of chlorophyll molecule and therefore essential for
photosynthesis.
2. An activator of many enzyme systems
involved in carbohydrate metabolism, synthesis of nucleic acids,
etc.
3. Promotes uptake and translocation of
phosphorus.
4. Helps in movement of sugars within
plant. |
1. Interveinal chlorosis, mainly of older leaves, producing a
streaked or patchy effect; with acute deficiency the affected tissue
may dry up and die.
2. Leaves usually small, brittle in final
stages and curve upwards at margin.
3. In some vegetable plants, chlorotic
spots between veins, and marbling with tints of orange, red and
purple.
4. Twigs weak and prone to fungus attack,
usually premature leaf drop.
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Sulphur (S)
1. Constituent of sulphur-bearing amino acids.
2. Involved in the metabolic activities of
vitamins, biotin, thiamine and coenzyme A.
3. Aids stabilization of protein
structure.
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1. Younger leaves turn uniformly yellowish green or chlorotic.
2. Shoot growth is restricted, flower
production often indeterminate.
3. Stems are stiff, woody and small in
diameter. |
Iron (Fe)
1. Necessary for the synthesis and maintenance of chlorophyll in
plants.
2. Essential component of many enzymes.
3. Plays an essential role in nucleic acid
metabolism affects RNA metabolism or chloroplasts.
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1. Typical interveinal chlorosis; youngest leaves first affected,
points and margins of leaves keep their green color longest.
2. In severe cases, the entire leaf, veins
and interveinal areas turn yellow and may eventually become
bleached. |
Manganese (Mn)
1. A catalyst in several enzymatic and physiological reactions in
plants; a constituent of pyruvate carboxylase.
2. Involved in the plant's respiratory
process.
3. Activates enzymes concerned with the
metabolism of nitrogen and synthesis of chlorophyll.
4. Controls the redox potential in plant
cells during the phases of light and darkness.
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1. Chlorosis between the veins of young leaves, characterized by
the appearance of chlorotic and necrotic spots in the interveinal
areas.
2. Greyish areas appear near the base of
the younger leaves and become yellowish to yellow orange.
3. Symptoms of deficiency popularly known
in oats as "grey speck", in field peas as "marsh spot", in sugarcane
as "streak disease''. |
Boron (B)
1. Affects the activities of certain enzymes.
2. Ability to complex with various
polyhydroxy-compounds.
3. Increases permeability in membrane and
thereby facilitates carbohydrate transport.
4. Involved in lignin synthesis and other
reactions.
5. Essential for cell division.
6. Associated with the uptake of calcium
and its utilization by plants.
7. Regulates potassium/calcium ration in
plants.
8. Essential for protein synthesis.
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1. Death of growing plants (shoot tips).
2. The leaves have a thick texture,
sometimes curling and becoming brittle.
3. Flowers do not form and root growth is
stunted.
4. "Brown heart" in root crops
characterized by dark spots on the thickest part of the root or
splitting at center.
5. Fruits such as apples develop "internal
and external cork" symptoms. |
Molybdenum (Mo)
1. Associated with nitrogen utilization and nitrogen fixation.
2. Constituent of nitrate reductase and
nitrogenase.
3. Required by Rhizobia for nitrogen
fixation. |
1. Chlorotic interveinal mottling of the lower leaves, followed by
marginal necrosis and infolding of the leaves.
2. In cauliflower, the leaf tissues wither
leaving only the midrib and a few small pieces of leaf blade
("whip-tail").
3. Molybdenum deficiency is markedly
evident in leguminous plants.
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Chlorine (Cl)
1. A constituent of auxin chloroindole-3-acetic acid which in
immature seeds takes the place of indole acetic acid.
2. Constituent of many compounds found in
fungi and bacteria.
3. Stimulates the activity of some enzymes
and influences carbohydrate metabolism and water holding capacity of
plant tissue.
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1. Wilting of leaflet tips, chlorosis of leaves and finally
bronzing and drying. |
Nitrogen(N)
1. An important constituent of chlorophyll, protoplasm,
protein and nucleic.
2. Increases growth and development of all
living tissues.
3. Improves the quality of leafy
vegetables and fodders and the protein content of food grains.
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1. Stunted growth.
2. Appearance of a light-green to
pale-yellow color on the older leaves, starting from the tips. This
is followed by death and/or dropping of the older leaves depending
upon the degree of deficiency.
3. In acute deficiency, flowering is
greatly reduced.
4. Lower protein content. |
Phosphorus (P)
1. A constituent of phosphatides, nucleic acids, proteins,
phospholipids and coenzymes NAD, NADP and ATP.
2. Constituent of certain amino acids.
3. Necessary for cell division, a
constituent of chromosomes; stimulates root development.
4. Necessary for meristematic growth; seed
and fruit development; stimulates flowering.
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1. Overall stunted appearance, the mature leaves have
characteristic dark to blue-green coloration, restricted root
development.
2. In acute deficiency, occasional
purpling of leaves and stems; spindly growth.
3. Delayed maturity and lack of or poor
seed and fruit development. |
Potassium (K)
1. An activator of enzymes involved in photosynthesis and protein
and carbohydrate metabolism.
2. Assists carbohydrate translocation;
synthesis of protein and maintenance of its stability; membrane
permeability and pH control; water utilization by stomatal
regulation.
3. Improves utilization of light during
cool and cloudy weather and thereby enhances plant ability to resist
cold and other adverse conditions.
4. Enhances the plant's ability to resist
diseases.
5. Increases size of grains or seeds and
improves the quality of fruits and vegetables.
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1. Chlorosis along the leaf margins followed by scorching and
browning of tips of older leaves; these symptoms then gradually
progress inwards.
2. Slow and stunted growth of plants.
3. Stalks weak, and plants lodge easily.
4. Shriveled seeds or fruits. |
Zinc(Zn)
1. Involved in the biosynthesis of indole acetic acid.
2. Essential component of a variety of
metallo-enzymes-carbonic anhydrase, alcohol dehydrogenase, etc.
3. Plays a role in nucleic acid and
protein synthesis.
4. Assists the utilization of phosphorus
and nitrogen in plants. |
1. Deficiency symptoms mostly appear on the 2nd or 3rd fully mature
leaves from the top of plants.
2. In maize, from light yellow striping to
a broad band of white or yellow tissue with reddish purple veins
between the midrib and edges of the leaf, occurring mainly in the
lower half of the leaf.
3. In wheat, a longitudinal band of white
or yellow leaf tissue, followed by interveinal chlorotic mottling
and white to brown necrotic lesions in the middle of the leaf blade;
eventual collapse of the affected leaves near the middle.
4. In rice, after 15-20 days of
transplanting, small scattered light yellow spots appear on the
older leaves which later enlarge, coalesce and turn deep brown; the
entire leaf becomes rust-brown in color and dries out within a
month.
5. In citrus, irregular interveinal
chlorosis; terminal leaves become small and narrowed (little-leaf);
fruit-bud formation is severely reduced; twigs die back.
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Copper(Cu)
1. Constituent of cytochrome oxidase and component of many enzymes
- ascorbic acid oxidase, phenolase, lactase, etc.
2. Promotes formation of vitamin A in
plants.
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1. In cereals, yellowing and curling of the leaf blade, restricted
ear production and poor grain set, indeterminate tillering.
2. In citrus, die back of new growth;
exanthema pockets of gum develop between the bark and the wood; the
fruit shows brown excretions. |
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Table 17 (Major Cations In
Water)
Constituents in Irrigation
Water ---Major Cations
| Constituent |
Symbol |
Equivalent
Weight |
Desirable
Range (ppm) |
Desirable
Range (meq/L) |
Comments |
| Calcium |
Ca++ |
20.04 |
40-120 |
0.2-6.0 |
Essential plant nutrient, occurs naturally
in most waters. Low levels increase potential for Calcium deficient
plants, but high levels are not normally harmful. |
| Magnesium |
Mg++ |
12.15 |
6-24 |
0.5-2.0 |
Essential plant nutrient, occurs naturally
in most waters. Low levels increase potential for Magnesium
deficient plants, but relatively high levels are not normally a
problem. |
| Sodium |
Na+ |
23.00 |
<50 |
<20 |
A non-essential nutrient, occurs naturally
in most waters. Can influence soil structure and plant uptake of Ca
and Mg (see Sodium Adsorption Ratio below). |
| Potassium |
K+ |
39.10 |
trace |
trace |
An essential nutrient, normally found in
waters in small amounts. Presence of more than trace amounts
indicates waters may contain fertilizer. |
| Ammonium |
NH4+ |
17.03 |
trace |
trace |
A source of Nitrogen (an essential plant
nutrient). Normally present in waters in small amounts. More than
trace amounts indicates water may contain fertilizer. |
Table 18 (Major Anions In Ground Water)
Constituents in Irrigation Water ---Major
Anions
| Constituent |
Symbol |
Equivalent Weight |
Desirable
Range (ppm) |
Desirable
Range (meq/L) |
Comments |
| Sulfate |
SO4- |
48.0 |
25-240 |
0.5-5.0 |
Contains Sulfate, an essential nutrient,
occurs naturally in most waters. Low levels increase potential for
sulfur deficiency, but high levels are not normally harmful. |
| Chloride |
C1- |
35.46 |
<70 |
<2.0 |
Occurs normally in most waters. Plants
require trace amounts. High concentrations are toxic to sensitive
plants. |
| Phosphate |
PO4- |
94.97 |
trace |
trace |
Contains phosphorus an essential nutrient,
normally found in waters only in trace amounts. The presence of
more than small amounts indicates water may contain fertilizer or
detergent. |
| Nitrate |
NO3- |
62.01 |
<10 |
0.12 |
Source of Nitrogen, an essential nutrient,
occurs normally only in small amounts. Presence of more than trace
amounts indicates water may contain fertilizer. The EPA Drinking
Water Standard is 10 ppm maximum. |
Table 19 (Boron And Flouride)
Boron and Fluoride
| Constituents |
Symbol |
Desired Range (ppm) |
Comments |
| Boron |
B |
<0.5 |
An essential plant nutrient, occurs
normally in most water. Low levels increase potential for Boron
Deficiency. High levels can be toxic to plants. When evaluating
Boron fertility, remember to include Boron supplied by fertilizer
and growing medium. |
| Fluoride |
F |
<0.75 |
A non-essential nutrient that occurs in
some waters and is often added to public drinking supplies. High
Fluoride concentrations can cause toxicity in sensitive plants. |
Table 20
(Irrigation Water Classifications)
Qualitative
Classification of Irrigation Waters
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Class 1 -
Excellent to Good |
Class 2 -
Good to Injurious |
Class 3 -
Injurious to Unsatisfactory |
| EC, ds / m |
Less than 1.0 |
1.0 - 3.0 |
More than 3.0 |
| Boron, ppm |
Less than 0.5 |
0.5 - 2.0 |
More than 2.0 |
| Sodium, percent |
Less than 60 |
60 - 75 |
More than 75 |
| Chloride, me/L |
Less than 5 |
5 - 10 |
More than 10 |
Table 21 (Water Quality Indices)
Maximum Acceptable
Water Quality - Indices for Bedding Plants
| Variable |
Plug Production |
Finish Flats and Pots |
| pH1 (acceptable range) |
5.5 to 7.5 |
5.5 to 7.5 |
| Alkalinity2 |
1.5 me/l |
2.0 me/l |
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(75 ppm) |
(100 ppm) |
| Hardiness3 |
3.0 me/l |
3.0 me/l |
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(150 ppm) |
(150 ppm) |
| EC |
1.0 mS |
1.2 mS |
| Ammonium-N |
20 ppm |
40 ppm |
| Boron |
0.5 ppm |
0.5 ppm |
Adapted from P.V. Nelson, Fertilization. Pp. 151-176. In:E. J.
Holcomb (ed). Bedding Plants IV. A Manual on the Culture of Bedding
Plants as a Greenhouse Crop, Ball Publishing, Batavia, IL (1994).
Used with permission.
1pH not very important alone; alkalinity level more
important
2Moderately higher alkalinity levels are acceptable when
lower amounts of limestone are incorporated into the substrate
during its formulation. Very high alkalinity levels require acid
injection into water source.
3High hardness values are not a problem if calcium and
magnesium concentrations are adequate and soluble salt level is
tolerable.
© SoilRenu Company 2011
SoilRenu is registered under U.S. Trademark Registration No. 3,023,544 |
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